Methyl 9H-xanthene-9-carboxylate
نویسندگان
چکیده
The title compound, C(15)H(12)O(3), was obtained unintentionally as the by-product of an attempted recrystallization from methanol of propantheline bromide, an anti-muscarinic drug. The xanthone unit is folded, with a dihedral angle of 24.81 (9)° between the benzene rings. The ester substituent adopts a trans staggered conformation, with a C-C-O-C torsion angle of 178.4 (1)°. The mol-ecules pack in distinct layers, facilitated by C-H⋯π and weak π-π ring inter-actions. A weak C-H⋯O inter-action also occurs; however, no classical hydrogen bonding is observed.
منابع مشابه
Methyl 7-methoxy-9-oxo-9H-xanthene-2-carboxylate
The crystal structure of the title compound, C(16)H(12)O(5), is stabilized by C-H⋯O hydrogen bonds and C=O⋯π inter-actions; π-π inter-actions are also present. With respective average deviations from planarity of 0.003 (2) and 0.002 (1) Å, the xanthone and ester fragments are oriented at an angle of 2.8 (2)° with respect to each other. The mean planes of the xanthone skeleton lie either paralle...
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